Quaternized Wood as Sorbent for Hexavalent Chromium

Carcinogenicity of hexavalent chromium.

Hexavalent chromium (Cr(VI)), a commonly used industrial metal, is a well known human lung carcinogen. Epidemiology and animal studies suggest that the particulate Cr(VI) compounds, specifically the water insoluble compounds, are the more potent carcinogens; however, the carcinogenic mechanism remains unknown. Here we summarize recent Cr(VI)-induced human tumour, in vivo, cell culture and in vi...

Microbial Reduction of Hexavalent Chromium

Publication 1. A. Manceau et al, “Quantitative Zn speciation in smelter-contaminated soils by EXAFS spectroscopy,” Am. J. Sci. (in press, 2000). Figure 3 (top) Soil samples were taken at several depths from a contaminated site. (bottom) Model compounds derived from polarized-EXAFS data at the ESRF and μ-EXAFS data at the ALS provide a good fit with powder-EXAFS spectra from a soil sample, there...

Quaternized Cellulose Hydrogels as Sorbent Materials and Pickering Emulsion Stabilizing Agents

Quaternized (QC) and cross-linked/quaternized (CQC) cellulose hydrogels were prepared by cross-linking native cellulose with epichlorohydrin (ECH), with subsequent grafting of glycidyl trimethyl ammonium chloride (GTMAC). Materials characterization via carbon, hydrogen and nitrogen (CHN) analysis, thermogravimetric analysis (TGA), and Fourier transform infrared (FTIR)/13C solid state NMR spectr...

Stable chromium isotopes as indicators of reduction and immobilization of hexavalent chromium in groundwater

Acute severe chromium poisoning after dermal exposure to hexavalent chromium.

Severe acute chromium poisoning related to dermal involvement has rarely been reported in the literature. We report a case of acute severe chromium poisoning through skin exposure as a result of a chemical burn of 15% of the body surface area and multiple organ failure after short-term exposure. Medical interventions, including mechanical ventilation, continuous venovenous hemofiltration, and p...